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Cu(In 4

Ga)Se₂ 3

X射线 3

二氧化碳 3

医院中子照射器I型堆 3

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CO₂利用 2

CO₂封存 2

CO₂捕集 2

COVID-19 2

催化剂 2

光催化 2

宏转录组 2

煤层气 2

生物转化 2

甲烷 2

碳中和 2

肠道菌群 2

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Overlooked nitrogen-cycling microorganisms in biological wastewater treatment

《环境科学与工程前沿（英文）》 2021年第15卷第6期 doi: 10.1007/s11783-021-1426-2

摘要：

• AOA and comammox bacteria can be more abundant and active than AOB/NOB at WWTPs.

关键词： Ammonia oxidizing archaea (AOA) Complete ammonia oxidizing (comammox) bacteria Dissimilatory nitrate reduction to ammonium (DNRA) bacteria Nitrate/nitrite-dependent anaerobic methane oxidizing (NO_x-DAMO) microorganisms Engineering application

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NiFeRuOxi>sub> nanosheets on Ni foam as an electrocatalyst for efficient

《化学科学与工程前沿（英文）》 2023年第17卷第11期页码 1698-1706 doi: 10.1007/s11705-023-2334-8

摘要： The electrocatalyst NiFeRuO_x/NF, comprised of NiFeRuO_x nanosheets grown on Ni foam, was synthesized using a hydrothermal process followed by thermal annealing. NiFeRuO_x/NF displays high electrocatalytic activity and stability for overall alkaline seawater splitting: 98 mV@ 10 mA∙cm⁻² in hydrogen evolution reaction, 318 mV@ 50 mA∙cm⁻² in oxygen evolution reaction, and a cell voltage of 1.53 V@ 10 mA∙cm⁻², as well as 20 h of durability. A solar-driven system containing such a bifunctional NiFeRuO_x/NF has an almost 100% Faradaic efficiency. The NiFeRuO_x coating around Ni foam is an anti-corrosion layer and also a critical factor for enhancement of bifunctional performances.

关键词： NiFeRuO_x nanosheets Ni foam electrocatalysis overall seawater splitting solar-driven system

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NOxi>sub> and H2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

《能源前沿（英文）》 2021年第15卷第1期页码 4-13 doi: 10.1007/s11708-020-0804-y

摘要： Low NO combustion of blended coals is widely used in coal-fired boilers in China to control NO emission; thus, it is necessary to understand the formation mechanism of NO and H S during the combustion of blended coals. This paper focused on the investigation of reductive gases in the formation of NO and H S in the reductive zone of blended coals during combustion. Experiments with Zhundong (ZD) and Commercial (GE) coal and their blends with different mixing ratios were conducted in a drop tube furnace at 1200°C–1400°C with an excessive air ratio of 0.6–1.2. The coal conversion and formation characteristics of CO, H S, and NO in the fuel-rich zone were carefully studied under different experimental conditions for different blend ratios. Blending ZD into GE was found to increase not only the coal conversion but also the concentrations of CO and H S as NO reduction accelerated. Both the CO and H S concentrations inblended coal combustion increase with an increase in the combustion temperature and a decrease in the excessive air ratio. Based on accumulated experimental data, one interesting finding was that NO and H S from blended coal combustion were almost directly dependent on the CO concentration, and the CO concentration of the blended coal combustion depended on the single char gasification conversion.Thus, CO, NO , and H S formation characteristics from blended coal combustion can be well predicted by single char gasification kinetics.

关键词： blended coal combustion NO_xformation H₂S formation air staged combustion

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H2sub> 对Pt-Ba-Ce /γ-Al2sub>O3sub> 催化剂NOxi>sub> 存储和还原机理的影响研究 Article

王攀, 裔静, 孙川, 罗鹏, 雷利利

《工程（英文）》 2019年第5卷第3期页码 568-575 doi: 10.1016/j.eng.2019.02.005

摘要：

本研究采用浸渍法制备了Pt-Ba-Ce/γ-Al2sub>O3sub>催化剂，利用实验评价了H2sub> 对NSR（NOx<结果表明，透射电子显微镜（TEM）显示X 射线衍射（XRD）光谱中观察到的PtOxsub>、CeO2sub> 和BaCO3sub> 峰很好地分散在在NOxsub> 完全存储- 还原实验中，NO2sub> 产量的增加使NOxsub> 的存储能力在250~350 ℃ 的温度范围内大大提高在NOxsub> 吸附和脱附循环实验中，随着H2sub>暴露时间（30 s、45 s 和60 s）延长，NOxsub> 的存储效率和转化率增加当稀燃和富燃持续时间分别为240 s 和60 s 时，催化剂的NOxsub> 最大转化率达到83.5%。

关键词： Pt–Ba–Ce/γ-Al2sub>O3sub> 催化剂，物理化学性质，NOxi>sub>存储和还原，NOxi>sub> 排放，H2sub> 还原剂

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of SrFeO/CaO∙MnO nanocomposite as effective oxygen carrier for chemical looping partial oxidation of methane

《化学科学与工程前沿（英文）》 2022年第16卷第12期 页码 1726-1734 doi: 10.1007/s11705-022-2188-5

摘要： Chemical looping reforming of methane is a novel and effective approach to convert methane to syngas, in which oxygen transfer is achieved by a redox material. Although lots of efforts have been made to develop high-performance redox materials, a few studies have focused on the redox kinetics. In this work, the kinetics of SrFeO_3−δ–CaO∙MnO nanocomposite reduction by methane was investigated both on a thermo-gravimetric analyzer and in a packed-bed microreactor. During the methane reduction, combustion occurs before the partial oxidation and there exists a transition between them. The weight loss due to combustion increases, but the transition region becomes less inconspicuous as the reduction temperature increased. The weight loss associated with the partial oxidation is much larger than that with combustion. The rate of weight loss related to the partial oxidation is well fitted by the Avrami–Erofeyev equation with n = 3 (A3 model) with an activation energy of 59.8 kJ∙mol^‒1. The rate law for the partial oxidation includes a solid conversion term whose expression is given by the A3 model and a methane pressure-dependent term represented by a power law. The partial oxidation is half order with respect to methane pressure. The proposed rate law could well predict the reduction kinetics; thus, it may be used to design and/or analyze a chemical looping reforming reactor.

关键词： chemical looping reforming SrFeO_3−δ/CaO·MnO nanocomposite reduction kinetics Avrami–Erofeyev model pressure-dependent term

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Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

《化学科学与工程前沿（英文）》 2021年第15卷第6期 页码 1561-1571 doi: 10.1007/s11705-021-2089-z

摘要： It is of broad interest to develop emerging photocatalysts with excellent light-harvesting capacity and high charge carrier separation efficiency for visible light photocatalytic hydrogen evolution reaction. However, achieving satisfying hydrogen evolution efficiency under noble metal-free conditions remains challenging. In this study, we demonstrate the fabrication of three-dimensionally ordered macroporous SrTiO₃ decorated with Zn_xCd₁₋_xS nanoparticles for hydrogen production under visible light irradiation (λ>420 nm). Synergetic enhancement of photocatalytic activity is achieved by the slow photon effect and improved separation efficiency of photogenerated charge carriers. The obtained composites could afford very high hydrogen production efficiencies up to 19.67 mmol·g⁻¹·h⁻¹, with an apparent quantum efficiency of 35.9% at 420 nm, which is 4.2 and 23.9 times higher than those of pure Zn_0.5Cd_0.5S (4.67 mmol·g⁻¹·h⁻¹) and CdS (0.82 mmol·g⁻¹·h⁻¹), respectively. In particular, under Pt-free conditions, an attractive hydrogen production rate (3.23 mmol·g⁻¹·h⁻¹) was achieved, providing a low-cost and high-efficiency strategy to produce hydrogen from water splitting. Moreover, the composites showed excellent stability, and no obvious loss in activity was observed after five cycling tests.

关键词： three-dimensionally ordered macroporous SrTiO₃ Zn_xCd_1–_xS visible light hydrogen production promotion mechanism

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Chemical poison and regeneration of SCR catalysts for NOxi>sub>

Junhua LI,Yue PENG,Huazhen CHANG,Xiang LI,John C. CRITTENDEN,Jiming HAO

《环境科学与工程前沿（英文）》 2016年第10卷第3期 页码 413-427 doi: 10.1007/s11783-016-0832-3

摘要： Selective catalytic reduction (SCR) of NO with NH is an effective technique to remove NO from stationary sources, such as coal-fired power plant and industrial boilers. Some of elements in the fly ash deactivate the catalyst due to strong chemisorptions on the active sites. The poisons may act by simply blocking active sites or alter the adsorption behaviors of reactants and products by an electronic interaction. This review is mainly focused on the chemical poisoning on V O -based catalysts, environmental-benign catalysts and low temperature catalysts. Several common poisons including alkali/alkaline earth metals, SO and heavy metals etc. are referred and their poisoning mechanisms on catalysts are discussed. The regeneration methods of poisoned catalysts and the development of poison-resistance catalysts are also compared and analyzed. Finally, future research directions in developing poisoning resistance catalysts and facile efficient regeneration methods for SCR catalysts are proposed.

关键词： flue gas DeNO_x SCR catalyst poison and regeneration

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Tailoring the simultaneous abatement of methanol and NO on Sb-Ce-Zr catalysts via copper modification

《环境科学与工程前沿（英文）》 2022年第16卷第10期 doi: 10.1007/s11684-022-1565-0

摘要：
● Cu addition enhances CH₃OH oxidation and alleviates its inhibitory effect on SCR.

关键词： Copper modification Sb-CeZr₂O_x catalyst NO_x Methanol Simultaneous removal

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Recent advances in special morphologic photocatalysts for NO removal

《环境科学与工程前沿（英文）》 2022年第16卷第11期 doi: 10.1007/s11783-022-1573-0

摘要：
● Systematic information of recent progress in photocatalytic NO_x removal is provided.

关键词： NO_x removal Photocatalyst Graphene C₃N₄ Bi-based compounds.

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用高光谱发光法研究Cu(Inxi>sub>,Ga1–xi>sub>)Se2sub> (CIGS)模块中由P1引起的功率损耗的成因 Article

César Omar Ramírez Quiroz, Laura-Isabelle Dion-Bertrand, Christoph J. Brabec, Joachim Müller, Kay Orgassa

《工程（英文）》 2020年第6卷第12期 页码 1395-1402 doi: 10.1016/j.eng.2019.12.019

摘要：
在本文中，我们利用了高光谱高分辨率光致发光映射技术，这是一个强大的工具，可用于选择和优化在Cu(Inxsub>,Ga1-xsub>)Se2sub>（CIGS）模块上对子电池进行图案化互连的激光烧蚀工艺。

关键词： Cu(Inx Ga1–x)Se2 电池到模块的效率差距 由P1引起的功率损耗 高光谱光致发光 激光烧蚀短程热效应

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CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction mechanistic study

《环境科学与工程前沿（英文）》 2022年第16卷第5期 doi: 10.1007/s11783-022-1539-2

摘要：
• CeO₂ doping significantly improved low-temperature NH₃-SCR activity on FeTiO_x.

关键词： NH₃-SCR CeO₂ doping Low-temperature NO_x removal Improved redox property In situ XAFS analysis

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Simultaneous removal of NO and chlorobenzene on VO/TiO granular catalyst: Kinetic study and performance prediction

《环境科学与工程前沿（英文）》 2021年第15卷第4期 doi: 10.1007/s11783-020-1363-5

摘要：
• A V₂O₅/TiO₂ granular catalyst for simultaneous removal of NO and chlorobenzene.

关键词： NO_x Chlorobenzene Simultaneous removal Kinetic study Performance prediction V₂O₅/TiO₂ Graphical abstract

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磁控溅射法生长的带隙可调谐(GaxIn1−x)2O3 Research Articles

张法碧1,孙巾寓1,李海鸥1,周娟1,王荣1,孙堂友1,傅涛1,肖功利1,李琦1,刘兴鹏1,张秀云1,郭道友2,王相虎3,秦祖军1

《信息与电子工程前沿（英文）》 2021年第22卷第10期 页码 1370-1378 doi: 10.1631/FITEE.2000330

摘要：采用磁控溅射技术和热退火技术在(0001)蓝宝石衬底上制备了多组分氧化物(GaxIn1−x)2O3薄膜，实现可调带隙。详细研究了三元化合物(GaxIn1−x)2O3在整个组成范围内的光学性质和能带结构演化。X射线衍射谱表明，Ga含量在0.11至0.55之间的(GaxIn1−x)2O3薄膜既有立方结构，也有单斜结构，而Ga含量高于0.74的(GaxIn1−x)2O3薄膜只有单斜结构。实验结果为透明导电化合物半导体(GaxIn1−x)2O3薄膜在光电和光伏行业的应用，特别是在显示器、发光二极管和太阳能电池的应用奠定了基础。

关键词： (GaxIn1−x)2O3薄膜；带隙可调谐；磁控溅射

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Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

《环境科学与工程前沿（英文）》 2017年第11卷第6期 doi: 10.1007/s11783-017-0976-9

摘要： N O is a powerful greenhouse gas and plays an important role in destructing the ozone layer. This present work investigated the effects of Pd doping on N O formation over Pt/BaO/Al O catalyst. Three types of catalysts, Pt/BaO/Al O , Pt/Pd mechanical mixing catalyst (Pt/BaO/Al O +Pd/Al O ) and Pt-Pd co-impregnation catalyst (Pt-Pd/BaO/Al O ) were prepared by incipient wetness impregnation method. These catalysts were first evaluated in NSR activity tests using H /CO as reductants and then carefully characterized by BET, CO chemisorption, CO-DRIFTs and H -TPR techniques. In addition, temperature programmed reactions of NO with H /CO were conducted to obtain further information about N O formation mechanism. Compared with Pt/BaO/Al O , (Pt/BaO/Al O +Pd/Al O ) produced less N O and more NH during NO storage and reduction process, while an opposite trend was found over (Pt-Pd/BaO/Al O +Al O ). Temperature programmed reactions of NO with H /CO results showed that Pd/Al O component in (Pt/BaO/Al O +Pd/Al O ) played an important role in NO reduction to NH , and the formed NH could reduce NO to N leading to a decrease in N O formation. Most of N O formed over (Pt-Pd/BaO/Al O +Al O ) was originated from Pd/BaO/Al O component. H -TPR results indicated Pd-Ba interaction resulted in more difficult-to-reduce PdO species over Pd/BaO/Al O , which inhibits the NO dissociation and thus drives the selectivity to N O in NO reduction.

关键词： NO_x storage reduction Pt/BaO/Al₂O₃ Pd doping N₂O formation Optimization

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NO hydrogenation to NH over FeCu/TiO catalyst with improved activity

《化学科学与工程前沿（英文）》 2023年第17卷第12期 页码 1973-1985 doi: 10.1007/s11705-023-2364-2

摘要： Ammonia is crucial in industry and agriculture, but its production is hindered by environmental concerns and energy-intensive processes. Hence, developing an efficient and environmentally friendly catalyst is imperative. In this study, we employed a straightforward and efficient impregnation technique to create various Cu-doped catalysts. Notably, the optimized 10Fe-8Cu/TiO₂ catalyst exhibited exceptional catalytic performance in converting NO to NH₃, achieving an NO conversion rate exceeding 80% and an NH₃ selectivity exceeding 98% at atmospheric pressure and 350 °C. We employed in situ diffuse reflectance Fourier transform infrared spectroscopy and conducted density functional theory calculations to investigate the intermediates and subsequent adsorption. Our findings unequivocally demonstrate that Cu doping enhances the rate-limiting hydrogenation step and lowers the energy barrier for NH₃ desorption, thereby resulting in improved NO conversion and enhanced selectivity toward ammonia. This study presents a pioneering approach toward energy-efficient ammonia synthesis and recycling of nitrogen sources.

关键词： NO hydrogenation synthetic ammonia 10Fe-xCu/TiO₂ high selectivity

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标题作者时间类型操作

Overlooked nitrogen-cycling microorganisms in biological wastewater treatment

期刊论文



NiFeRuOxi>sub> nanosheets on Ni foam as an electrocatalyst for efficient

期刊论文



NOxi>sub> and H2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

期刊论文



H2sub> 对Pt-Ba-Ce /γ-Al2sub>O3sub> 催化剂NOxi>sub> 存储和还原机理的影响研究

王攀, 裔静, 孙川, 罗鹏, 雷利利

期刊论文



of SrFeO/CaO∙MnO nanocomposite as effective oxygen carrier for chemical looping partial oxidation of methane

期刊论文



Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

期刊论文



Chemical poison and regeneration of SCR catalysts for NOxi>sub>

Junhua LI,Yue PENG,Huazhen CHANG,Xiang LI,John C. CRITTENDEN,Jiming HAO

期刊论文



Tailoring the simultaneous abatement of methanol and NO on Sb-Ce-Zr catalysts via copper modification

期刊论文



Recent advances in special morphologic photocatalysts for NO removal

期刊论文



用高光谱发光法研究Cu(Inxi>sub>,Ga1–xi>sub>)Se2sub> (CIGS)模块中由P1引起的功率损耗的成因

César Omar Ramírez Quiroz, Laura-Isabelle Dion-Bertrand, Christoph J. Brabec, Joachim Müller, Kay Orgassa

期刊论文



CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction mechanistic study

期刊论文



Simultaneous removal of NO and chlorobenzene on VO/TiO granular catalyst: Kinetic study and performance prediction

期刊论文



磁控溅射法生长的带隙可调谐(GaxIn1−x)2O3

张法碧1,孙巾寓1,李海鸥1,周娟1,王荣1,孙堂友1,傅涛1,肖功利1,李琦1,刘兴鹏1,张秀云1,郭道友2,王相虎3,秦祖军1

期刊论文



Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

期刊论文



NO hydrogenation to NH over FeCu/TiO catalyst with improved activity

期刊论文